Resonance In Chemistry

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Resonance structures are two forms of a molecule where the chemical connectivity is the same but the electrons are distributed differently around the structure. Resonance occurs when electrons can flow through neighboring pi systems. An important example of resonance is found in the bonding of benzene, a planar six-membered ring with alternating double and single bonds (three of each). Two distinct pictures can be drawn, and the true structure of the molecule is a mixture of the two resonance structures. Having multiple valid resonance structures makes a molecule more energetically stable. Resonance helps to explain structure and reactivity of organic molecules.

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This is the first part of two closely related reviews prepared for Magnetic Resonance in Chemistry dealing with the computation of 31 PNMR chemical shifts in a wide series of organophosphorus compounds and including analysis of accuracy factors, such as substitution effects, solvent effects, vibrational corrections, and relativistic effects. Nov 10, 2010  How to Study the Resonance Effect in Organic Chemistry. The resonance effect describes the polarity produced in a molecule by the interaction between a lone electron pair and a pi bond or the interaction of two pi bonds in adjacent atoms.